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The interactions between the sterically demanding trimesitylphosphine oxide and trimesityphosphine with scandium and selected lanthanide ions

PLATT, Andrew and Singh, Kuldip (2016) The interactions between the sterically demanding trimesitylphosphine oxide and trimesityphosphine with scandium and selected lanthanide ions. Journal of Molecular Structure, 1111 (online). pp. 180-184. ISSN 0022-2860

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Abstract or description

The reactions between lanthanide nitrates, Ln(NO3)3 and scandium and lanthanide trifluoromethane sulfonates, Ln(Tf)3 with trimesitylphosphine oxide, Mes3PO show that coordination to the metal ions does not lead to crystalline complexes. Investigation of the reactions by 31-P NMR spectroscopy shows that weak complexes are formed in solution. The crystal structures of Mes3PO·0.5CH3CN (1) and [Mes3PO]3H3O·2CH3CN·Tf (2), formed in the reaction between ScTf3 and Mes3PO, are reported. Trimesitylphosphine, Mes3P, is protonated by scandium and lanthanide trifluoromethane sulfonates and lanthanide nitrates in CD3CN and the structure of [Mes3PH]Cl·HCl·2H2O (3) is reported.

Item Type: Article
Faculty: Previous Faculty of Computing, Engineering and Sciences > Sciences
Depositing User: Andy PLATT
Date Deposited: 18 Nov 2016 16:28
Last Modified: 01 Feb 2017 01:38
URI: http://eprints.staffs.ac.uk/id/eprint/2919

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